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81.
82.
We analyzed C and N stable isotope ratios of benthic fauna and their potential food sources at an intertidal methane seep site and a control site without emanation at Mocha Island (central Chile). The objective was to trace the origin of the main food sources used by the local heterotrophic fauna, based on the hypothesis that chemosynthetic production could be partially fueling the local food web at the seep site. Food sources sampled at both sites included macroalgae, particulate organic matter and bacteria-like filaments found growing over the red algae Gelidium lingulatum within the areas of active methane release.  相似文献   
83.
84.
The Jalisco Block is thought to be part of the Guerrero terrane, but the nature and age of the underlying crystalline basement are largely unknown. We have collected a suite of schists, granitoids, and weakly metamorphosed marine sediments from various parts of the Jalisco Block including Atenguillo and Ameca, Mascota and San Sebastián, Cuale, Puerto Vallarta, Punta Mita, Yelapa, and Tomatlán. The schists range in age from 135 to 161 Ma, with many exhibiting Proterozoic and Phanerozoic zircon ages. The granitoids range in age from 65 to 90 Ma, and are calc-alkaline compositionally—similar to granitoids from the Puerto Vallarta and Los Cabos batholiths. The Jalisco granitoids also experienced similar uplift rates to granitoids from the regions to the north and south of the Jalisco Block. The marine sediments yield a maximum depositional age of 131 Ma, and also contain a significant zircon population with ages extending back to the Archean. Granitoids from this study define two age groups, even after the effects of thermal resetting and different closure temperatures are considered. The 66.8-Ma silicic ash flow tuff near Union de Tula significantly expands the extent of this Cretaceous–Paleocene age ash flow tuff unit within the Jalisco Block, and we propose calling the unit “Carmichael silicic ash flow tuff volcanic succession” in honor of Ian Carmichael. The ages of the basement schists in the Jalisco Block fully overlap with the ages of terranes of continental Mexico, and other parts of the Guerrero terrane in the south, confirming the autochthonous origin of the Jalisco Block rather than exotic arc or allochthonous origin. Geologic data, in combination with geochronologic and oxygen isotopic data, suggest the evolution of SW Mexico with an early 200–1,200-Ma passive margin, followed by steep subduction in a continental arc setting at 160–165 Ma, then shallower subduction by 135 Ma, and finally, emplacement of granitoids at 65–90 Ma.  相似文献   
85.
Using semivariogram parameter uncertainty in hydrogeological applications   总被引:1,自引:0,他引:1  
Geostatistical estimation (kriging) and geostatistical simulation are routinely used in ground water hydrology for optimal spatial interpolation and Monte Carlo risk assessment, respectively. Both techniques are based on a model of spatial variability (semivariogram or covariance) that generally is not known but must be inferred from the experimental data. Where the number of experimental data is small (say, several tens), as is not unusual in ground water hydrology, the model fitted to the empirical semivariogram entails considerable uncertainty. If all the practical results are based on this unique fitted model, the final results will be biased. We propose that, instead of using a unique semivariogram model, the full range of models that are inside a given confidence region should be used, and the weight that each semivariogram model has on the final result should depend on its plausibility. The first task, then, is to evaluate the uncertainty of the model, which can be efficiently done by using maximum likelihood inference. The second task is to use the range of plausible models in applications and to show the effect observed on the final results. This procedure is put forth here with kriging and simulation applications, where the uncertainty in semivariogram parameters is propagated into the final results (e.g., the prediction of ground water head). A case study using log-transmissivity data from the Vega de Granada aquifer, in southern Spain, is given to illustrate the methodology.  相似文献   
86.
We present the results of a palaeomagnetic study of four mid-Cretaceous limestone sections exposed in northeastern Mexico. The limestones are weakly magnetized and exhibit two- to three-component magnetizations. These magnetization components appear to be carried by both a sulphide mineral and a magnetite-titanomagnetite mineral. The sulphide mineral carries a reverse polarity overprint that often makes it difficult to isolate definitively the higher-unblocking-temperature component. The high-unblocking-temperature component is well defined in the upper portion of the Santa Rosa Canyon section and in the Cienega del Toro section and passes the fold test. The characteristic remanent magnetization (ChRM) inclinations agree well with predicted mid-Cretaceous inclinations for these sites, although the declinations differ by more than 100°. The relative rotation between these two sites probably occurred as the thrust sheets were emplaced during Laramide deformation. At two of the sections, namely Cienega del Toro and the overturned Los Chorros sections, only normal polarity directions are observed. The La Boca Canyon and Santa Rosa Canyon sections exhibit zones of both normal and reverse polarity magnetization. Correlation of these polarity zones with the geomagnetic polarity timescale provides a time framework for lithostratigraphic and palaeoceanographic studies of these sections.  相似文献   
87.
Filter feeders such as bivalves are increasingly being shown to control phytoplankton blooms in eutrophic estuaries. The possibility of such a top-down effect on macroalgae, however, has not been considered previously even though most green tide algal species reproduce by pelagic swarmers that are equivalent to phytoplankton. This work presents circumstantial evidence from an oyster-culturing French embayment where, despite eutrophication since the mid-1970s, macroalgae did not proliferate until 1982. This was also the year when tributyltin pollution from antifouling paints dropped substantially following a world-wide prime ban that was implemented to save the shellfish industry. From the recorded evolution of the oyster stock, it is shown how tributyltin reduced the bivalve filter capacity within those years and resulted in Enteromorpha swarmers being much more likely to germinate and bloom. This suggests that the green tides had been successively contained by the biological activity and the chemical pressure. The effects of the latter on the former would thus have cascaded to ecosystem-level changes, and so the functional role of bivalves should be evaluated and preserved wherever relevant.  相似文献   
88.
Aeolian dune dimensions and migration rates are analysed along the Ceará coast, north-east Brazil. Dunes that are currently mobile along the Ceará coast are composed of barchans and sand sheets. The results show that barchans maintain an equilibrium form, which can be characterized by values of dimensionless shape parameters H/W and W/L , where H is the dune height, W is the wing-to-wing width and L is the dune length. Dunes are highly mobile, with average migration rates of 17·5 m year−1 for barchans and 10 m year−1 for sand sheets. The calculated migration rates were found to depend strongly on dune dimensions for both barchans and sand sheets, i.e. the larger the dune is, the lower the migration rate will be. This size dependence was associated with the existence of a representative common transport rate along the dune fields, which induces a different dune migration rate dependent on dune size. Finally, from the observed dune evolution, an aggregated scale aeolian sediment transport was inferred. This bulk transport rate, of the order of 90–100 m3 m−1 year−1, is only valid for a timescale of years to decades, which is the timescale used in dune evolution analysis.  相似文献   
89.
Extracellular peptide hydrolysis rates were measured in seawater and sediment from Flax Pond salt marsh using peptide analogs (LYA-peptides) as substrates. This technique allows the direct measurement of specific hydrolysis products and thus provides insights into enzymatic hydrolysis pathways. In sediments, hydrolysis rate constants of LYA-peptides varied seasonally and with depth. Highest activity was found in spring and summer, and most cores exhibited a subsurface maximum. Calculations using the concentrations of chemically-measured peptides suggested that extracellular hydrolysis of peptides is faster than the rate of free amino acids uptake. However, not all peptides may be available for enzymatic hydrolysis. In both seawater and sediment, extracellular hydrolysis of peptides of up to 8 amino acids yielded smaller peptides and free amino acids. Hydrolysis rates depended on size of the peptide substrate, although a clear relationship with number of amino acid constituents was not evident. Peptides containing >2 amino acids were hydrolyzed 10–400 times faster than dipeptides or the fluorogenic substrate Leucine-MCA. Thus, dipeptidases are either uncommon in nature, or hydrolysis is carried out by nonspecific hydrolases that with a low affinity for dipeptides. This is also suggested by the presence of a lag time before dipeptide hydrolysis begins, and the absence of dipeptide hydrolysis in 0.2-μm-filtered. One implication of this finding is that measurements of hydrolysis rates using substrates like Leu-MCA may not accurately predict the magnitude of hydrolysis rates of macromolecules in the marine environment. Even though dipeptide hydrolysis is slow compared to that of larger peptides, LYA-dipeptides are preferentially produced from the hydrolysis of larger substrates. LYA-dipeptides do not penetrate cell membranes of microorganisms because of their size, but natural dipeptides are smaller and can be transported across the cell membrane. Since dipeptides do not appear to accumulate in natural waters, they must be rapidly removed by microorganisms.  相似文献   
90.
Conversion of waste biomass into valuable functional materials accomplishes the concept of circular economy in the development of sustainable waste management, and also recovery of such resources possibly reduces the requirement of feedstocks. In this scenario, the development of methodologies toward the direct conversion of the raw biomass into solid adsorbent materials without the use of any templates is highly desirable, but exceptionally challenging due to the complexity of the process. Here the direct synthesis of 3D porous carbon traps by a simple, cost-effective, and template-free process starting from a kitchen-based recipe and fermented food waste is described. Precisely, a robust carbon trap is formed with a spongy structure and highly interconnected hierarchical pores after the pyrolysis of a rice-based foam in the air. The developed materials float on water and interact efficiently with cationic dyes at static conditions. Importantly, such performance of the 3D carbon traps is not affected in the presence of anionic dyes, indicating the excellent selectivity towards the adsorption of cationic dyes. The adsorbent can be easily recovered and reused for up to 3 cycles without releasing any byproducts, thus, without causing hazardous risk of any secondary pollution to the environment.  相似文献   
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